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Page 1: I! tsïepubs.surrey.ac.uk/848455/1/10804004.pdf · 2018-06-22 · 0-y s>oo Ob 30 04 03 'Tneo'RETiQfii^LY ^ c.c. NsiOCl soLs^r SHoUL^yiet^ e.g.Oxv* "fH60'R£T7Cfl/-t./ O'ôy M(?. tAnO

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ProQuest Number: 10804004

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INFORMATION TO ALL USERS The quality of this reproduction is dependent upon the quality of the copy submitted.

In the unlikely event that the author did not send a com p le te manuscript and there are missing pages, these will be noted. Also, if material had to be removed,

a note will indicate the deletion.

uesL

ProQuest 10804004

Published by ProQuest LLO (2018). Copyright of the Dissertation is held by the Author.

All rights reserved.This work is protected against unauthorized copying under Title 17, United States C ode

Microform Edition © ProQuest LLO.

ProQuest LLO.789 East Eisenhower Parkway

P.Q. Box 1346 Ann Arbor, Ml 48106- 1346

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i.ae 1 . Î3 a«ec , I- 2.81 .V9 3.$Ü

I f C 5 l^ e re l e i l l i o a t ' t - r rc ::^u hue r t i n $ f .

f r e e c f f c t ^ e iC 'T C f , In ^ t^ ; ; ' ' : o f th e u u v a l th *^ ;% )e n lT \ite u *( : : ' ;u . : i i i f % i? ) . ' . ' .

% h/-i j ; r r c " f u r @ d n u c r ib o l u to ^ e ?r \G ü ; ^ l l e d to'c o t a l t $ c ;nu l4^.,ru7b l3 ' Z uuu yc3*u&r,^^%a,te f j r z e o l* .

n i r e o i ^ ^ D a o f c o t% I t r u u ' t i j i a l I nf . . ' r ; : : e t r i o c z t i i z a t l r l l f f l e o l c ^ o / l n ; ; th v d A r l^ r e n o o I n Tl'^G t u b e 'en t i n u t u n l ^ r i % / l , / l e # . .

Ib 3 f i l t r a t e ; : t - . z t : ' ! f . ^ r e e r ie r * Theytc f : 'y n e u l: ,% S z ^ 2 ^ l9 e ' i n * i3 4 t e .ui;- Ü4,]2'cr

c : « .n i m o tl) . %t.X c r J r r i z . n t r i c . t l l y(,T : ) " , e r - y r l l l r ^ ( 3 . ' c o . I t i l n t e C ln j3 0 Z ! . I # 1 1 )# C ':!;, trAce..^ o f a c " ; r r ""%%e f c n n : * u n i th o u o ^ I dne., . . . f . ' o t t i n t i n t c f th ) ; r r : ,n 't tz #

i \ V 1 'f n t . : J 1,^5' .

( 1 ' # I* )'W ll n i l l.CO 4.00

. ...03

. t ' -ü-^l. I r l«; t . f 3 îr%, fh- *)

3 .1 : j . l^F - . 1 1.34

n * e f C 'T ' " r r i l h In f.»Ztr%tè*( "3 % j

q .c ;$o .o i O.OÈ 0.08 : e#G3

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c f th e c c r y e r i n t o th re n * t i t . n K & lz tu ro I n m f r r m 'w b W b u c lu b le m n l n e t re ":.i! lZ yI t foL73? t h , t ) I f te CO ; c r hmZ rrc;'b8cc% ^acormruti;l u : * trc v ^ n f i c c c u le n t % rC G i: lt '% tn * ( o . r ^ l o t r M

jc r ju b " '! vn I k r T r f 'u e n c v o f o e n 3 lL io r ;,U IeîUtJVJfcfr. If?-tt n3b, ^ }* iLi* denn blrcm % red'It At rh&ee dmd net ceeür, ar? th»' K eunt cf ;cr::r'n'" n7,t'; fcrmci n m f' r fron% thectra.tio:ly ncf

I h t ' a ^ i r t c l A b l y iner.;;.^3 '>d b y f u r t h e r t r r m t in s n t c l th e r diuc. TMc lu in L re-mnt 7lth thvi rori: cf R. Kflller*( '* . & " c r j# Cuce*. 19 f , 1 1 ? # 4 1 ? ^4 2 2 )^ on Ih e fc rm m tlo n ù f c c r r e r r e r o x l l e t y th o & c t* e n c f t y t e o h l e r l t e cn c e : i 3 f I l l : O f f e u n l t b i t he o e u l l o b t:d .n th n y o l lc m u û lu t lù n c f rC '^ro riC u

y k y th e u u e o f m, e lm . r b lu e m lL i i I in e o f c o ; i e r o z l l o ,n A r c uy z j m t j d r o z i l o I n i^cod* b'? o e ^ l^

th 3 e f c l t ^ - ^ r th ? y e l lc \ ? r ^ - r e ^ i l o■1 ■fjj .iUt.i' >,#'' 4*

m l

&@k c ; ; e re %11

" n^n t b r r e t i e d d o c o r l t e l &beve„(pa»g$ 8* l i n e 1 )$ l i . r c ih ' f w c b n W c f K, n g u ia te ( * W v e B &#*- ignO)# th e r u m n t i t y o f : . f & \n r^ )n c t.3 fc r z e d d l . n e t re u e b th e t M r r e - l ^ - a l v d a o

: :' 1 )V • /1.1 - n i ' 4Amt* o f 13,%.':,

( a;; * " , T |13,0':' 4 f * i J x:-..~' 1

0

I t , eC ; 'n-f ."y nit"» tcrrcd » u. ,C r; IT " , ) 1

1"', 'T 11 eg . X.' # ‘ V

It n u thcucht th t tils might be riac to th{) yrw kture d e o c r re c lt ic n c f t r * t u f f i r )%oliLtl<n by le-%, c f curbon l l e s i l e I j f r t ' - t>s^ c :n im i: . , t lv o ly lu r ü - o f bml Lez-necnvcrt4:>l to %cn. ngw\;.tc. Zo retard tllo Icuu mu f. .r mu ^ c u u lb l iP , t b ) c% e r i : : o n t c % 'cfo ro y e -u te d i r l t h t : e e f \A eticmrr o f O'lrbcn d lc z l le to? u o lu t lc n thehfAtlng# It tbo end ef tlrcmi.lnutnu* fizilobucIlR: th"' rAGnA:; cC tw l'i%rtbrr 1C c.c. cf ceduz', .h y ;o c h lê r itv & i : :d f re n m b u ro ttc # A f te r . fu r th e r t«^r .. m ln u tc c ^ b o t t lD g # th e i f i l t / r c l

mu Lcfcrv*& n l th J T o rn f.n '& n m ti

: "T Y j V 1' : ' / i T )f t o f Tz'T '-.ncr*!^ (m.i L"»C. ) 9 , #4 %,i 1 •’'«. ! ‘‘Ÿ w,- ...<’* J- f ^

s,* r r ' .n.^i.n.aiW fe r& f 'O ;/ C US M : 6. # Î - 3 ) 3 . F / , II J. «'9 ..

I:y t h j r ;^ ^ th c d * r r m e t lo m l ly i& I l tM ,m & D g .& n e m .,

"':tu e rn v e r tO 'l tn p a irm n r ;z ;& te , au I n t!%.> em&e # h e r# mm&l * U 4 % :t^ tio u c f m uni-A rrucï vm re t u i s n , : - -

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eiu/vmleut cf dcmo:<% curlurut'hyreobloTlt %n vuu DfLmcox cn Tvr.lny mmtll

. tbr) cnlutlcn r r u e b ' f i ti' t»T. t,.. In u, lli.:r longul li rc, OA-x, it ;o,.ulble to Cctoet

cdcriretf.eulZ) any èoeietiuB In cJLd tbi jgiici itutcj* tc- Wn ty th::' Llm;,:bb%tî%r ('*l'3etcd

.sniy trAoxm cf tu.' %=lcn cL'Alt v/tu u,,bstltutc4 Ter;ùê%Z5:n$fp a%reùt,«ûl0 «.rvunt of %cr -*%«...* r%Cuôed#y It la eriC'rt* tb r'fure* thet rr/crum rt;,,c31rn ij

I''- n:x): cf û'i or# ti'vrn T±i'n ;rLot:ouifyby tc'flcrlt''" È.ir.3 t'm c,',t>lTtlc tljy c:io» I littler\' 1- rcr&:&d by tt" o.vivT.'i ry mc'.irn cf tk? tUkai* but thlu r-y b re cnvcrhcl tc 'er" r; Y$.ti in Tiltrat '* ziu klroi\iy ; ' .

2 z !lt fL J z Z J Z J 3 i .'Itt rcr rd to th? effcot of kn:' %rc, T-rtlon c* c<'%;cr

to r"n ";n^-Le cn th"' ccuru"' cf th.,' i_;?etlcu, th~r crtltn% r»,t*e . .

la ret .,0 Tvelu'-'drflnci aA Ij the c...ue mith et5'"''r f tetqra, "f '7%ric:* conslJcruLly mcccfdlSt; tc t:«e uirGUL'utAncus, far I'Oierito wU.cuntu cf r:An,/u.'''esj (l t rj* U-/ irrmcDm #ftb T ulrdvnt r:Ui,ztlty uf CL icr ti, lb' l(Utbrt, rlkb *oL%t of m (ov r C L: 0)* the%r'CT.nao cf A.%\re lc\/0ly ef CsC*::' eIs not f %cur Ile to cor; lot yreol ltutlon cT tb'" cc%-' or#

Gf c-bt JLyut rocultu in & rei&tively r. li dccc /euitlon (f by;cohjcrlte rlttcut ; Tco;titly f,r;utATlng the cm;..or ,n*bc fcrc,.tion, T'Ould kdso tkê / .

cffeot of render:Curve 1 leu.# mtcer* mn'' zzulmylnr t!": mctdnz'/odt 'T th':: r lue* ZJitb mclormte -u'tuntz of.&,rcAe9(s 6.n\* Vtfy 3i).ill %nzxntltlem o f on, .zzr% M .

fr.C',?.tieD lu lnoer;let:# :#c Zi:r3 mnl C,lt C..L . -.yleiael 3,?C: î nO (ms lj)0). Th4vrn.ch$7* and r *',1 ??lwn more.ty cchlcrito; it yielded m Urthor t.rs K r'rO ., : A third. treu,t mt of tm %ycjr: tet!3 -C-re C *C 5 1*- * jfw.zzG^*

IncrecLoe in tr,o r itic of oobmlt to m«.nA'nooc ohO;:5 a m&Tked tendency to docreuo the cf ; crx.nuAnute formed*

212212#'Utb r ixrd te thj w:L 1.13*33 th't

cou ld t c d ^ te o t.- l by tL i.> Lo tb -'d , the l i m i t ^ y re m rf'l te d^&renl . cn the kevvnt cf y . ü r i c.r&blo of freducing % visible t j r t * C #0C 3 t j . mmnjAneje ("-u bnO) coavarted to. tb# . thc-fr- tioul mr.crat of tbiu Au%coo* only,C*C o*n. cnJiui byiocbiori' f C.2 c,c, joliuu cep or m r b c n ; t * u e lu t l fu j'^cro u : : ' i ; ^ qu n t j ' y c f h / O L b la r lte'cad i 5 ru;.A t i e p T "A r f ,n a . tc c o lrm r vitb » .,y e lle e l» b tint*, .

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*y '**0

..'cunt cT fromTcrezldm. 1 O'* lu esucrbZel ric r jtitration ?lt3 tyfror-'r mro:.lc%; ri, con, byz^rochlcrlo mol': c iUl L.-> in t':- flltr.iL''' irufu th't vobAltrosi'fuo* an4* losuibly* aluo c of cblcrlo &cll duoto ccMTcrslan cf byr^^ohZcflt''* Irto chi,.rate

I t r ; j fcmnd th%t . - .

( ] ) U diuA bypcoblurlto c*a 1% cocplet^fly cujtrcyol by W iling.- r ith ccLult u.Ut ctlutlca# . , -

$.5 3,0# L",nj 1 j'_e. Cccf IS W llln;. h'l nu tit#'

. i-Sf ,5* ^ iP If, _-■- 4k 4#. #*»/&,* #

(.;) At ccnuilor&,Ule dïlytlcnj* *" 3 'Tc cne in t:c in i- hich i t *- jvUd be fcn,)f:'d a*srluticn, Cc u net to have aziy nurcolarblo cffnct cn thetitre cf pen u.n .ritte r l t t bydrc^oa perorl ''t Tb"'

.mntltlAj of cnZor^tc mf;? b-*

Âi A m % .y,"W wjA.yl#* %y '12 ^ Xp,\

Âtth':' CDi

/ i f mr.rnito i r tuc

o f h y d r c o b lc r ic t n r S k C ic i f lc a t i r .n c f th

prO':rnrc

3C o . e . ty^.O f. ; : / inouncoin

. n l lm r i y n o r io o ^ t.w .,C '^ in lr n l_______ _ I - * , ? : ,e# ' a ,:uo. f t ' r L c l f ^ i r i c t t i e n p.'■«-%.! I roa--------------------- .8

.c, n/l". r'nO,s. coin, i . srcio-î

,3# % *"«Ÿ* '

'r.'* Title n f 4* amd

( 3 ) n i t h u l lG À t l yno C n c ^ r j - c u l t l c n , cf u llx ll &icnc* th:

CC1:% q.r:(yCU*Lylrc:,:.:! tercxlde.

(&..A.A 'a: c n

r / p 1*«. »' H ? c , %*' .11202-in >-' 1

hy;; c n h l c r l t o * , o n : t n c u f f e r en j . '!ckl6> 1 ^ * 0 t i c

trm u o c f m t u y t l t c u n o t ^ p % r '^ c i^ ^ b ij t»:;* t l t r ^ ?d.*"b

■ .' .’V .t -, '.'X... r;' -:/» < ■■ ' :-!< %JF'*k- • lA'Æ-.'i-'S.',ti*:A4v44*- ‘.-Wrt-è

c:LU:t f^.tul to c;

lb' ;rc iuwfthc ' 't% lim T* h "*c?or. I t ;x, g fcnnl th&.tcc ..^p ..lu *.tlL^no '"-ere c^Lk-e '! b y th p r c c m jo c f c u t a l t c ^ t y c i r c a *

h t l t i ' a ; l e n v a lu e d pnzx) o b t A ln c i ?ztrn r o V o r a W * ;::e u n t#?rlc'l cf

( I )ct,w J t %zalt (c L - :; , ) v.'f^rr^ w t c n l^ t W ncrmu,:W i i i ' ^ r (15 mino,) ( Ivcn.( 3 1 ) l o " ' t i t r & t l e n v . , * lc e j c b t ^ in e d T-hm p r c t r a c t e d b o i l i n glo

cut) ,nd ?7Mrc g t l l l ^ . r t h v r d .::c rcu ,.c ; %?lLnl.rg-er of ret I t ,

y» 1 > m i«UV»- '.«■• .■■■■■• ., ri »,- '.a:, -' •■ ,/ ft K.T"j *,4ü 'K tu r e . ic m e CJLb e l l i n g .

T l l n t - l i t r L L ,n l I I / « 'C r^ r / 1 A f Oo *>AJk t 3 m m % oei

,;1i', C ■’!(>■ # Wi*. # "«MV** ■ ak-âa *. V C # Cf' »^•••«Vf* 4.«., ••'. # .Jfjd Û # C * 15 r i n . . ' m i l ,

10 & 15 1 6 ■ 1 0 ,5 'IG ,. 2% ' S JLC 3.1 ,110 2 ' 35.. 9 . 64 fS. ' . rI v e W . ................... .*.v S' . . ; : 30 ' .-7

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tiz o r e v w B e r f \ 3 t l o n p i w eto A o r L l l escW nt wh$# o c b A lb l e ?$ I B ) , SZheao.d r a"b%e&3 r e n d e r tW T r lu m e it r io m c t W l uT% '^;ltp ,b to f ^ r tu-* f f k»*.* rno&ng&n&tc forc.' i In tir* r arctic n rhea ocbult Ij Lü'*2 &ia -

>

Page 15: I! tsïepubs.surrey.ac.uk/848455/1/10804004.pdf · 2018-06-22 · 0-y s>oo Ob 30 04 03 'Tneo'RETiQfii^LY ^ c.c. NsiOCl soLs^r SHoUL^yiet^ e.g.Oxv* "fH60'R£T7Cfl/-t./ O'ôy M(?. tAnO

' . Il ; cC cob'ilt* mltheugb large eenei>ntr%tiem# cf. mlkàll" t' , i j e . . I l r e r L ^ t I : n # .

' (a). Gtber Wln. mn g&ne a. ioul# '. h# eemplf tely eziél eê # là etqepper* tha'marna#.çn wb&It l3 U- d*.howéve * ## percentage p#nmû3gan#e . . " . . .

fcni)ed d#r0;am-m lm. a regular Wanner Mthlnere&ulng. eumW -. .

2%tüs<k3ü&3;2%s, ' . .'; - .' . . . ' , _ . -(3) fhe form %nd the :ûêa eff L /t ,1 L. Mff f , rc,%sO!u#. C:;L\l oreeb.lt

. la' flccoulant* . difficult W filter*, &#i . . .'prem ete .# etÿ-.^en frœ % w hyp#ohicrlte ' \ . . . . . .

L.rvri^ut t'c' T' irtlci# , T W ceppef 41% flrht ,

. .fl#c/ô2lé#* e#w &dm.a#hiwk. residù#*and Wùme$. oem.##er%hly l$;s$ active #a fagàrâ# '- ;

. typeehlôrite tien* fWr th% f#mation thé. /.' .p e f6 â u # :.:.n a te h & ^ t # # n p lm c e * . .. . ' .

" ' (4) Th@ échoit... h"' L ' '' ' h , fci t ' - '* :l^ *, .*1;..carbonate* : Ca nmt b# #m:pl#%ely ep&fated fmm. the wl%.tl%n % Wiling* i$ tW c' e #lth :E20ier%c %a%D%iti$a ef

. . ' ' . ^

.. l ù c A / / y % % %. '% t ' f'Ixc'/lD; %r,t b i p r / ^ r '. %b# würua igf th'3 a&in\re#ctW%$* .am# 1# %lth

f&qt:î demefibea .in.tM,fi re#i.mg.pm,gea$ effect cf..the .hypechlairlt/p i# capter pémzl# &mi'hy#<&Wâriàhg%nem

. . . .Ihe éxldatlen %c.pe.rm.angAn&Mj* .# 1c. A l'jt uL ig-eynj'" cf n 21:he* lu ',%ly «..cc»l''v t Uly t: -"X 'f T :'Tic% it-e. ory: o$ p, ;::b:y

. . thro;agh '% n;rxr- ::T= in* rr.c Xte.fcrçmtl cf a%. cc#$#n&i l r : "» .ut 1. i t: t C" *1:

A t X l e ctAçc much cf hy%:chlcrl%3 be 'n ieeci'pcc?!*&%M. tW mncmntrgiWm* .due te.tw alK ll #lch 1# neçea mrlly.T' c t W : 1 n% zXr#%e #:K'qem cf lew ba$ an Inhlbltlve efrwt cm t w .

cf .frcsh c#p$r #ere%lde* m4 rewtlom 1# .

If* hc ever.#. t.t# c rW &te blc&rWm&W mimtmré uaed*(1) itx buff r aetl-m rcn\fu tDe Influtncc ef W: Cl,11 ne liyible* mW W %W cf th# ç#X':' tt pr cl It.X î* '

'.izMh cf t:c rart #f tw reactiw Wlej Im tie lilu lij* o%lu*Uon CL *"! Cf ej/i pr te o: Zet\n#

%v.a't#*3^ : $#me ê v l# n e e f e r t h # # .f . $ u c # mmc X ' " e W u % : 7 . : r * " t b r % \ 0 A ,

% f th e 'm a n ^ a ie .w m.m4 c e p p $ r .c u lW . .se p a ra te ly ., ' ; . . . .

.h ÿ p e é h lê T iW .' W f c r # th o . ccm h lm .e l a e l u t i w s -^ i t h . . ' f u . r t W r . % C a # i t y 'e f W p e c h le .& iW * . tb # .wimmmt c f pen%&m$&n&ta

I s $ ^ c h l e s s th & B th m t cb ta l.% eâ by th e m ctle rn o f . ' .

h y e e h l c r l t ' '3 m ir ' '" * m a lts * . . . . . ' . , .

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e&js ib<&

( 1 ) A t . - th e m a o w t o f '.: rrn"ur(.?3:*to I 3 f. rx"! t:r nn: cf uL'..ut thrcomlnut;:':*. . , boiling*. KM. after ef 0%; .third of tW tetai . .

{2 ) Th ouo icicn.C fgrmaticm a Wmls3j Qolour/l.m #m aoluL mXn. 1% ' r ' ae tl 3T is due t@ the f b y '

cf al.\ Jj t#@ permal%gU3&W* . - Ifc L ZL_.u:,l6 c\,n to .' : r-'-cc 1 verted. W ps: r5;x%E.n.àt@ by Wan-a of a mlKtmre

.. r f ut JiiwL::' 1 in?\i û.: »:(j,13 .aj d mâ.lu.m ' hyp. oohlorlte, :.. . y -. ' . -

(2 ) Ts3 LyJrciyZ icm cene/rmtr&tion Im & very i*"Xrtrnt fpstzzr\ in LODncCwJcn nlth tto optent ef .remotion, C::3y l i uppmtn T Ir.

^ ^CK,J r , w " 1 / t *

(4) if- of cc* yr %Zt:* t\":l unXr f\Vcir,itlacomiitlL%o* rixng'noiAS su,lt3 (%: 15 up.) ein b'* cz'-p). zc -ly

to r/.rr.uTg-cata In tliu rcAutZrm.

(5) ranotlcnu cf ocpp-jf of c. ;zJLt a.: outxJymt.im.'the :.' rt'Acticm emucntlally-difftrott. ' . .y..' . y ' . -

( ) Umd- r th' renlltltrj cf ti; e cf rewtiea .y...{.uiiei, tho but;: ruajtlcm 1 n'Xll iblo# .. '. '. /- ,.. '

(?) tto cf cepiur ..In th$? r^aetlcn In . .. . . .

k:x* for'* cf kb'" of bh- rsaellcn e&%. 1) " . . . ..

Am (A ttciyt to ##tiW.&te..VGlub;etrjCuù.ly XK- err ng. mxbafcruci the roA.atiua * but -this .#m;â fovni to bj Impruotlc/Lilc.


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