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Mff ero rrpoxo~eHHH tIepea ra90xpoMaTor~SCKYD KQJIOHKY CTenBHIo p8Sshy
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1l1 B 2 pasa BNDle ISM UpH o De It PaBHIL1ICfI (55 0 plusmn 4 0) ]laInBelliDse
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He KlIc~oA CpSIUl Ha HS~TpamHy1O II mMOffiY ( OTC)lC Blle IlpOIJYKT8 IIpJJshy
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lsmre 2 I8C OB KaK llpll OOC TaR H rrpH 20degC BSPOfITHO llplIcOeIOllieHIlS acshy
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(45 plusmn 4 ) n pR T8MIIsp3Type rexPc 3a I Iac nalte IIpR TaROH BHCOROn KOHshy
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BHSHBaST y romaeHJle TOT ~T ITO llpZ MaJlHX KOHIJeHTpamRX ZJIOpHnshy
Jpound J BeJIlImR8 ROHCTaHlU nllCCOInI~ ROMlJJI8KCa At ce - no o~eBKaIO p aBHa 25IOr 2
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rltY C TaOllJll3HpyeTCR B ifloIlM8 rWloaCT8THo A KlCJIOTH - At 0 H 3 4 Hanwme ROTOPOH n 03BOJIfI8T ocyme CTBlfTJ p~ rrplllcoellHH9HIUI aCTaT8
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JMbHWi areHT - IrpOTOHHpOBaBHYlO r mIOaCT8 TlfYlO KKC)lOTY Po t OH l bull ITo
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BaJIeHTHOr o KaTlfOH bull B 3aKJIlOIeHH9 aBTOPbI BllJl8ICWOT r JIYooRYla 6JtarOnaPHOCTlgt 13 A Xamurny
3a IIOCTO~ WiTepec It IlamIoil pa6o T9 li ueHllli8 aaMBI3HJotJ1 IO C KOPOTshy
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MeTOlllJ 3KCU9Ill4MeHTa Tl opramtlecKoli JCmm1
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7 centgts13HKa RCflbI X 1c10H O B 2 p 85 lton
8 Kp~1oreHlo1K 1 2 p 85 Ko n
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10 ABTOHan-13auaR 06pafioTK~ 3 Kcne p~HeHT m bHblX
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11 El~ 4HCn~ - E Jl I Ha fi MaH~M clTIo1Ka H TeXHI1K3 6 p 80 Kon
2 XHM1R p 70 Kon
13 l cXH01 Ka cent ~ 3~14e cKoro 3KcnepHMeHTa 8 p 80 Kon
14 H c cneAoBaH~A TBepA~x Ten 101 ~HAKOCTC~
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15 3Kc ne p ~Mc H larlbHaA ~~3~Ka ~AepH~X pcaK4~~
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18 Hc nonb 30 DaHHe pe3 Yfi bT aTo e H Me TOA O B
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pa B XJlopHoH KHCJlOTB OnHCaHO B pa6oTe~ bull
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c IOIe rpa3H o6~eIIDfl11IH H coxpaHmra IlpH TeMTlspaType OoC HrteHT~HItaUIDO 3TIDIeHScTa TllUUmra lIpOB0rtWlli MeTonOM raSOJlGltKOCTHOn XP0MaTOrpaPmr
rrpR TeMllepaTYPe 1200C MCITOJIbsOBanH CTeKJIaHHHs ROJIOHKK ~O~ 2 M
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JIO mlMSH8Hli1Ji oclIqero Elma XPOMaTOrpaMMN C rteJThlO ItOCTOBepHoft 1I)(8HTHshy
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HIDl Ea gt lDIDKlX IPas ax (Ta6Jr I ) futIeXCbl ~epmmamJll aTOIO coeItXHe-
IIHR n OJlllOCTfJO COBIlalI9IlT C ZHnexCaMH ynspumaHlJt 3llLlenacTaIIl1UCPmta
cBHTesEpOBaHHor o DyTeM HYKJI~RJIIgtHOrO 3aMeIqeHBR XJIopa 8CTaTOM B s~shy
JIeHXJlOpIlIZij)BHe B TIpRCYTCTBllI aMmJOB no M8TOny OIllcrumoMy B pa60Te7lt
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T= 1200C 1
X CRBaII8H AmIesoH Tpmcpe3lU1lgtOClPa T
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10392 plusmn 0 2
6570 plusmn 04 7530 plusmn 0 5 879 1 plusmn 02 981 3 plusmn 0 2
10478 plusmn 15 II52 plusmn 9 8 1299 0 plusmn 3 4 13876 plusmn 6 6
ItO _900e TOJIYOJI II aaTSM IIoBTopno BBOnWICH B lasolKHJUocTRID1 xpor8TOrshy
p~ ilYTeM cpaBHeHHH pal(HoaRTllBHOC TR rroBTopHO BBOnHMOrO 3THJISaaCTaTshy
r lfIUlIDi8 )10 11 IIOCJIe xpOMaTorpag)HpoBaHKR onpeIeJllIJICH ITpoueHT ero p83JIoshy
nIDm Jia rBsoXpOMaTOlpaqnecRoi KOJIOHK9 0xa3aJIOCb ITO IIPR Bli6pamna
YCJIOBHIIX BHanH3a (20 5 plusmn 1 8) 3TRJIeHacTaTTBnpRHa pSSJIaraeTCJt BO Bpashy
Mff ero rrpoxo~eHHH tIepea ra90xpoMaTor~SCKYD KQJIOHKY CTenBHIo p8Sshy
JIoJeIntlI OKaeaJUlC OIUIHaKOBOlt Il)III mgt6oM mI Tpex HCnOJIbsyeMHX llJItlOX
1Pa3 B TO lW Bp 9Ml RaxOIVICb B XJIOPcxPOPMS TIpIl OOC 3TltJIeHaCTaTrlllij)llH
coxpaHKJI CBOD YCTO~OCTb B TetIeHHS 5 ~COB ( Bee nocne~e ~shy
HUe rIpnOIVITCH B HBCTomlleA CTaTbe C Yl6TOM CTeII8HH pa3JIOampeHWl aTHshy
JI9HBCTSITHJJplIH8 ITpH 810 rasoxpOMaTOrpallRl9CKOM BHaJIH3 S) BvIo yCTashy
HOBJIeHO ITO Be60JWlJoe YBeJlll1iOHlIS TBMIIepalYPll YCKOpilBT pealWKD IlpHshy
coeItHHeHlllf Tax IlJll 600e 3a 5 MmfYT BLlXOI lTWI8HacTaTI1llij)lIHS 6liJl nolshy
1l1 B 2 pasa BNDle ISM UpH o De It PaBHIL1ICfI (55 0 plusmn 4 0) ]laInBelliDse
OOBbllDeHlilS TSrmSpaTypH IlpIIBOlllJIO K CRltlKeHDl BllXOM no IlplJlUlH8 TepMZshy
qeCKOIO pacnartP IIponyRTS
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IOJlJUO OM3IlBaTb CYDleCTBeHlloe BJmStHHe Ha BIlXOI 3TMeHacTaTIBJJPIDIa
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KllCJIOTliOCTlI cpeIOl BIlXOn 3T1JIeHaCTaTI11fl(pHHS pe3KO BOspaCTaeT B pattOHe
pli OT 03 no 3 aTa 38BBClIMOCTb Bocn IIpRMOJJJmetUnrt xapaKTep B aTOM
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C POCTOM pH cpenw xapaJltTep peaxtrlDf ~leruteTCR DoItoponmrx HOHOB
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He KlIc~oA CpSIUl Ha HS~TpamHy1O II mMOffiY ( OTC)lC Blle IlpOIJYKT8 IIpJJshy
J lIID HOn8 KOHCTaHTa rtHCCOIlIaDIIH r OM ITO OCHOBHOMY THITY paBHa 310-10 8
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lsmre 2 I8C OB KaK llpll OOC TaR H rrpH 20degC BSPOfITHO llplIcOeIOllieHIlS acshy
TaTa B ~OM c~ae H8 rrpo~CXO~T B~ OTCYTCTBRR He06xo~oro
IIpOTlIBOBOHa lLIm liS ITO llplIIHHe HaxOJleImfI aCTaTa B TPYIUIOAHCcolllillpy eshy
MOM COCTOmIJllll MB B IWyrOH XHMlIIeCKoi ~pMe
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(45 plusmn 4 ) n pR T8MIIsp3Type rexPc 3a I Iac nalte IIpR TaROH BHCOROn KOHshy
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BCTYllaIJllleS B peaKItBJ) npJC oe~eHHfI
BHSHBaST y romaeHJle TOT ~T ITO llpZ MaJlHX KOHIJeHTpamRX ZJIOpHnshy
Jpound J BeJIlImR8 ROHCTaHlU nllCCOInI~ ROMlJJI8KCa At ce - no o~eBKaIO p aBHa 25IOr 2
5
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rltY C TaOllJll3HpyeTCR B ifloIlM8 rWloaCT8THo A KlCJIOTH - At 0 H 3 4 Hanwme ROTOPOH n 03BOJIfI8T ocyme CTBlfTJ p~ rrplllcoellHH9HIUI aCTaT8
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BaJIeHTHOr o KaTlfOH bull B 3aKJIlOIeHH9 aBTOPbI BllJl8ICWOT r JIYooRYla 6JtarOnaPHOCTlgt 13 A Xamurny
3a IIOCTO~ WiTepec It IlamIoil pa6o T9 li ueHllli8 aaMBI3HJotJ1 IO C KOPOTshy
KHHY 38 n OMOmP B IIpoBeneHRH o6~eH~ na YCKopHTe~9 Y-2oo
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MeTOlllJ 3KCU9Ill4MeHTa Tl opramtlecKoli JCmm1
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p323J-32 t J ro fiaH r1gty-lt31lB liopc eSB IOB XBnxml BA Tiao Tao-HaRlo laIUiOXIDOOi
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6 ~AepHaR cneKTpOC Kon~ R H paAHOXHMH R p 80 Kon
7 centgts13HKa RCflbI X 1c10H O B 2 p 85 lton
8 Kp~1oreHlo1K 1 2 p 85 Ko n
g YCKopHTeni-1 p 80 Kon
10 ABTOHan-13auaR 06pafioTK~ 3 Kcne p~HeHT m bHblX
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11 El~ 4HCn~ - E Jl I Ha fi MaH~M clTIo1Ka H TeXHI1K3 6 p 80 Kon
2 XHM1R p 70 Kon
13 l cXH01 Ka cent ~ 3~14e cKoro 3KcnepHMeHTa 8 p 80 Kon
14 H c cneAoBaH~A TBepA~x Ten 101 ~HAKOCTC~
Fl A e pl-lblMH Me TOA~1r~~1 1 p 70 Kon
15 3Kc ne p ~Mc H larlbHaA ~~3~Ka ~AepH~X pcaK4~~
np~ H~3KHX 3Hep r~AX P 50 Kon
16 n03HHel p ~ ~ H ~H3HKa 3 a~HT~ P 9 0 KOtl
17 Teop~1R KOHAeH c~pO BaHHo ro COC T ORHj1~ Ii p 80 Kon
18 Hc nonb 30 DaHHe pe3 Yfi bT aTo e H Me TOA O B
centYHAa~HT a n b H blX Q41 3 t1 4eCK~X l1Ccne AO Batf Hi1 2 p 35 Ko n S CMe ltfHbl X o 6n a C T A X HayfltH l T CXH~ KH
19 5V1ocentl~3j1Kas ro=~ ~ s 11 l fut Ltlt oI MlJilli Cl Ubl lL cxtJQ PW eHa C JWJ60ro MeCA ~
g r= ni l III I M UIH1L)lC tM oqopM-n eHM A nOAnHCKH c nCAYC TsO
IJi OI1~fl 111)0 cy 10 1000 MocKBa Ill aB no 4TanT tgt COt
= ~ ro = coo o Q) ot[ Q) ~
arro E-lt E-t = gtos E-lt cd os C) E-t
o= rOS s I=i 0 c s 0
IS r= a~ ro s() tr s Q)=~ ~O c O 0 o~s
29shy1 n 20 Ko n
a TC WYUl C r o rOAa
06pa1ijaTbcn B 3qa T e Jlb CtltMi1t
nR 79
3RCn9pgMeHT~Raa gaCTb
ACTaT 00Jr nOJIYI8H rryTeM 06JJYI8HHSl M8TaJlIllN8Cl(OrO BHCMYTS WlIgtIIashy- -qaCTZUaMK C meprlIroi 36 MaB H3 YCROpETeJIe Y-200 na60paTOplIlI HDSpHllX
pearotH1 OI1ffif ~eJIeHH9 a CTaTa 113 Mmlle~ IlpzroTOBJIeIDlB era paCTBoshy
pa B XJlopHoH KHCJlOTB OnHCaHO B pa6oTe~ bull
3TlJIell 3TMeBXllOp~HH (M9pR ofgtpr ) XJIOpolJOPM XJIopg811 KHCshy
)lOTa H rloUWOKC1I)( HaTplUl (tI bull It a ) liCITOJIbSOB8JJHCIgt 6 es rtOllOJIIDlTeJThHOa
OllCTKH HacUllIBHKe paCTBOpoB XJIOPRoit RlICJIOlbl (rmux)(Clila IlaTpWl lLIIH
BOIJH ) 3TH1l9HOM IpOBOnwrOCb llpK TeMIIep aTyp9 OoC BpoII- H lIoI aTR1leHr~shyp ER 6~ ITpzroTOBJIeHH no CTaBltapTHo cxeM9 OUHCaHHolt B ~epaTYPe 6~
lIIuI nOJJYI9HKll 3TltJI9HaCTaTIlUijJBHa n o p eaKItHll 3JIeKTpoqMhllOrO
ITplICOBlKHeHKff B aMITYJIH 06~eMDM 0 2-0 3 MH ITOMemanz 100 MRJI nacwmeHshy
Hor o 3TlJIeHOM 05 M p ac TBopa XJIOpHOn KHCJIOTIl II 10 Mlt1I Taxor o xe lIa
ItlCJIOTHOCTR p acTBopa aCTaIa AMnyJlll 3 aIIaKBaJII H BbU(eJllKllB8JlX 30 MmlYT
rrplI OOC 3aTeM HX BCKPIlBanH Io6aBJliLiIlI R CMeCR IO MKJI Hac~efffioro No ce pacTBopa lI BblIreJIflJIll 3THJIeHa CTa TIHlPIDf C nOMOIJ4bH) 3ItC -rpaRlllD
XJlOp c$gtpMOM ITpR OOC JteyxpaT1811 ( no I20 MlUI) 3RCTpaKUrui n03BOJWI8
UOJIHOCTbIO H3BJIetn IIpOJJYKT n pHCOelOffi9HliI a c raTa K STMeRy OpraHHleshy
c IOIe rpa3H o6~eIIDfl11IH H coxpaHmra IlpH TeMTlspaType OoC HrteHT~HItaUIDO 3TIDIeHScTa TllUUmra lIpOB0rtWlli MeTonOM raSOJlGltKOCTHOn XP0MaTOrpaPmr
rrpR TeMllepaTYPe 1200C MCITOJIbsOBanH CTeKJIaHHHs ROJIOHKK ~O~ 2 M
y BHYTpeHHlM IUIaMeTpoM 4 MM sanOJIHemme xpOMocop 60M W- )MC S coneplIalIIJM (IO-I5) JlGWlaquo)lt 1Pa3H B RaqeCTBe XlmKoit 1Pa3i owm BSHTbl
CKBaJIaH anB630H H TPlIKPe3RJllOCIPaT r aaOM-HOClITeJIeM c nyJkKJI r eJmlt n oshy
naBaeMlrll B ROJIOHKy co CKOpoCTM) 80 wtMlm
PeaYXLTaTY H o6c~eHKff
Ewro 0 6nap]X6ao iTO IlJlIl Bi6paHHIgtIX YCJIOBHfIX e1tHHCTBSHHNM llpOIIYKshyTOM p eaKllHlpound IlJlHCOeltIDfeRM aCT8Ta R 3TiDleHy JIBJIlIeTCJt 3llLleHaCTaTllmshy
pmr Ha BiXOnS H3 r asCllllDltOC THoro JCpOMaTOrpapa He clWo sapeIBcTpBpOshy
BaBO mmaIOtX npyrn KpOMS Hero oprSKJrliecKHX ~PM COIteplllalIlBX aCTaT
YBeJIWlelmS lICXODHO YI8JllHO~ aKTZllHOCll BCTaTa B 5-10 p as He BblSIlB8shy
JIO mlMSH8Hli1Ji oclIqero Elma XPOMaTOrpaMMN C rteJThlO ItOCTOBepHoft 1I)(8HTHshy
~mtanD npoJlYKTa npRcoellllHeHllS 6wm onpeIteJlelW erc ml(eltCs ynepmma-
HIDl Ea gt lDIDKlX IPas ax (Ta6Jr I ) futIeXCbl ~epmmamJll aTOIO coeItXHe-
IIHR n OJlllOCTfJO COBIlalI9IlT C ZHnexCaMH ynspumaHlJt 3llLlenacTaIIl1UCPmta
cBHTesEpOBaHHor o DyTeM HYKJI~RJIIgtHOrO 3aMeIqeHBR XJIopa 8CTaTOM B s~shy
JIeHXJlOpIlIZij)BHe B TIpRCYTCTBllI aMmJOB no M8TOny OIllcrumoMy B pa60Te7lt
Urur OneHKlJ XBWrl8CKOrO BliXona 8TltII8HacT8TlJOJPlIHa aoo6xoItBMo clHJIO
OnpeneuTIo yCTO~OCTb ero lIpR r a soxpoMaTOrpalJaq8CKON aH8JIlJ9S l)It
STOro BWCOItBlll1IA RS ROJIOHKH 3T1JIeHaCTaTrlJIijllni co6HpaJIC1I B ox~aelold1
2
TaomB 1 lliiISI(CS yneplItHB8lIRII CHzX - CH2 0H (rne X = ce Br I H At ) HB pa3Jl1tIHllX JmIUtHX W83ax IlJllI TGMIlspaType
T= 1200C 1
X CRBaII8H AmIesoH Tpmcpe3lU1lgtOClPa T
ce 8r I At
73lt3 5 plusmn 19 832 9 plusmn 12 955 1 t 0 3
10392 plusmn 0 2
6570 plusmn 04 7530 plusmn 0 5 879 1 plusmn 02 981 3 plusmn 0 2
10478 plusmn 15 II52 plusmn 9 8 1299 0 plusmn 3 4 13876 plusmn 6 6
ItO _900e TOJIYOJI II aaTSM IIoBTopno BBOnWICH B lasolKHJUocTRID1 xpor8TOrshy
p~ ilYTeM cpaBHeHHH pal(HoaRTllBHOC TR rroBTopHO BBOnHMOrO 3THJISaaCTaTshy
r lfIUlIDi8 )10 11 IIOCJIe xpOMaTorpag)HpoBaHKR onpeIeJllIJICH ITpoueHT ero p83JIoshy
nIDm Jia rBsoXpOMaTOlpaqnecRoi KOJIOHK9 0xa3aJIOCb ITO IIPR Bli6pamna
YCJIOBHIIX BHanH3a (20 5 plusmn 1 8) 3TRJIeHacTaTTBnpRHa pSSJIaraeTCJt BO Bpashy
Mff ero rrpoxo~eHHH tIepea ra90xpoMaTor~SCKYD KQJIOHKY CTenBHIo p8Sshy
JIoJeIntlI OKaeaJUlC OIUIHaKOBOlt Il)III mgt6oM mI Tpex HCnOJIbsyeMHX llJItlOX
1Pa3 B TO lW Bp 9Ml RaxOIVICb B XJIOPcxPOPMS TIpIl OOC 3TltJIeHaCTaTrlllij)llH
coxpaHKJI CBOD YCTO~OCTb B TetIeHHS 5 ~COB ( Bee nocne~e ~shy
HUe rIpnOIVITCH B HBCTomlleA CTaTbe C Yl6TOM CTeII8HH pa3JIOampeHWl aTHshy
JI9HBCTSITHJJplIH8 ITpH 810 rasoxpOMaTOrpallRl9CKOM BHaJIH3 S) BvIo yCTashy
HOBJIeHO ITO Be60JWlJoe YBeJlll1iOHlIS TBMIIepalYPll YCKOpilBT pealWKD IlpHshy
coeItHHeHlllf Tax IlJll 600e 3a 5 MmfYT BLlXOI lTWI8HacTaTI1llij)lIHS 6liJl nolshy
1l1 B 2 pasa BNDle ISM UpH o De It PaBHIL1ICfI (55 0 plusmn 4 0) ]laInBelliDse
OOBbllDeHlilS TSrmSpaTypH IlpIIBOlllJIO K CRltlKeHDl BllXOM no IlplJlUlH8 TepMZshy
qeCKOIO pacnartP IIponyRTS
~f3YleHHe iOlHe TBlUl perutIllDI lIpR oOe IlOKa3aJIO (puc I) ITO B nepshy
BHe IO MXHYT Ha~eTca p e3KHH POCT BHXOl8 KOTOpuR naCTBraeT 65 3a 15 - 20 MRl1Yr H MJIOS OCTaeTCR noc TOmntIDd He M8HIDiCb co BpeMSHeJl
~3B9CTRO ~o p6aRUBII IlpHcoBItHHeBBR TKEC~ raJIOrSHOB K H9R8CUshy
m9IDlllM yrneBOnoJX))(illd HBJIfleTCJI reTepOJIllTBtIeCKOa J1oCROXLKy OHa ~
IaeT 3JIeKTpoqlIIIlHyIl a Taxy no lJBoihJO~ CBII3K TO TIpHCYTCTBle RlICJlOlbl
IOJlJUO OM3IlBaTb CYDleCTBeHlloe BJmStHHe Ha BIlXOI 3TMeHacTaTIBJJPIDIa
~13 38BHCIDAOCT1 TIJl9nCTaJ3JleHHol Ha pRC 2 BJIltHO ITO TIpH YB8JllfIemm
KllCJIOTliOCTlI cpeIOl BIlXOn 3T1JIeHaCTaTI11fl(pHHS pe3KO BOspaCTaeT B pattOHe
pli OT 03 no 3 aTa 38BBClIMOCTb Bocn IIpRMOJJJmetUnrt xapaKTep B aTOM
IDnepBaJle pH p8aJtItBF[ npHCOe)~HellIDi JmeT B OCROBHOM C yq8C TReM nposhyTOHKpOBar1Hotl lHnOaCTaTHoi1 JUICJIOIl - (AtOti
2 )1 bull
C POCTOM pH cpenw xapaJltTep peaxtrlDf ~leruteTCR DoItoponmrx HOHOB
~TruOBHTCR MeHLm~ II B p9aKJJHR aneRTp~HOrO ITplICOeItHHeHKH rrpSBaJIZshy
~
~80 25 ~ r
u 60 A ~ sect ~
40
_J o 5 10 15 20 25 30 35 MHH l
PRC I 3aBHCHMOCTlgt BHXo~a 3TH~8HacTaTr~KHa
OT BP8MSHE P eaKqHR
l~ =[o 80 i5-50
sect ~I~ 30 ~ t 20
IO
l 0 8 10 n 12 13 gt4 pH
PHC 2 3aBHCHMOCTn BhlXOM 3TMsHacTaTIRlJJ)lma OT
KHC~OTHOCTH cps~
pym88 yqacTRs 6yn8T TIpHHRMaTlgt MeHee peaKlllloHHocnoc06HrtI aJIeKTpOltPRIIDshy
HHll ar8ET - rmzoaCTaTHM KHC~OTa (AtOH ) PaspliB CMSll At- OH 6~eT TIpOllCXO~Tn BHYTpll TIpoMeJKYlOIHOro KOMllJI8Kca BBany Toro ITO rIDIoacshy
TaTEM rurcMTa JIBJIffeTCR cna6blM aJIeKTpoPMoM II ~CCODlaIULI ee ITO OCHOBshy
HOloY Tllny saTpYILHlIT8JThHa) BIDCOn llTRJI8HacT8TIlIlij)KHa nana eT IIpll CMeshy
He KlIc~oA CpSIUl Ha HS~TpamHy1O II mMOffiY ( OTC)lC Blle IlpOIJYKT8 IIpJJshy
J lIID HOn8 KOHCTaHTa rtHCCOIlIaDIIH r OM ITO OCHOBHOMY THITY paBHa 310-10 8
4
COertHHeHIDI B cpene e pH paBHHM 13 H 14 MOJKeT 61iTlgt 06yc~oB~eHo KaK
ITO~aB~eHlIeM ~llCCODl8UID AtOH TaR H BOCCTaHOMeImeM aCTaTa ~O a CTashy
T~) IIOI(06HOS nOBe~eHIle aCTT Ha6iIKu8JIOClgt H B p6aKDIIH aneKTpoPRlIbshy
Horo apoWlT1ll8CKOro SaMem81I11ff 4 bull P8~ HMe8T SaM8THIil1 BIDCO~ TOJThshy
KO upH nO~Hc~eHHlI cpe~
P8~ llpBC08nHHeHHff He ~eT upH 3aM8He r~OKcMCO~8pxamsro
paCTBOpHTenH-BOIUl Ha ~OpoPOpM CMH~ xnOPoPOPMOM co CT8HOK CT~shy
Hoi aMITY~ aCTaT IIoc~e ero ~C~ C cepe6pa B nyc~ aMIIY~ He
B3aHMO~eftcTBo~ C 3TM8HOM llpll B~epXKBaHIIX p8~OHHOH CMeCH B TSshy
lsmre 2 I8C OB KaK llpll OOC TaR H rrpH 20degC BSPOfITHO llplIcOeIOllieHIlS acshy
TaTa B ~OM c~ae H8 rrpo~CXO~T B~ OTCYTCTBRR He06xo~oro
IIpOTlIBOBOHa lLIm liS ITO llplIIHHe HaxOJleImfI aCTaTa B TPYIUIOAHCcolllillpy eshy
MOM COCTOmIJllll MB B IWyrOH XHMlIIeCKoi ~pMe
IIpR BBe~eHlIH B peaKItlIoHHylO CM8Clgt (aCTaT B 015 M H(lO~+ (Hit 6BXpOMal-ROH8 KOHD8HTpaIUre~ IO-7M HS 6i1I0 OOHapJ)teHO IIpOnyKTOB IIpHshy
CoenHHeHKR acTaTa It 3TRJISHY 3a I laC TIpoBenemm peruanm TIpR OOC lloshy
BHllieHIle TeMIIepaTypli ITO Bcef B~OCTJJ cIIoco6cTBYST ~cco~
ROYnnSRca II IIOSBO~eT nO~HTlgt 3TKnSHaCTaTr~lIH C BHXO~OM ~o
(45 plusmn 4 ) n pR T8MIIsp3Type rexPc 3a I Iac nalte IIpR TaROH BHCOROn KOHshy
oeHTJ)8DIIH 6HXpOMaT-HOHa KaK 1O-2M ilpHCYTCTBIIS B PSaKllIIOHHOi CMecR UOplUt-RoHa IIpHBO~T K CHIDlWHBJO
BllXo~a 3TM8HaCTaTrHIWIDIa (TaM 2)
Tao~a 2 3aBHCRMOCTL BHXOM 3TRJIeHaCTa~lIHa OT KOHIJSHTpaIJHlI
NoCe (YC~OBKff 002 M Heeo T8MIIepaTj1l8 - oOe
BpeMff - 30 MHHyT)
o 10-5 ro-4 IO-3 10-2
IBllXO~
( ) 455t35 443plusmn46 48 6plusmn79 22 5plusmn45 i 12 4zP 8
AAaJIOIlIUlYe OIIHTH rrpoBenemme C Hon0M-I31 des HOCJIT9JlJI llOR838shy
JIll no~o6HHe pesymTaTH Bep01JVO ac TaT B KlIc~oi cpene B rrpltCyTcTBmt
XJIOPHn-l[OHa TaK lEe R8R J HOll o 6paay eT TP~O~ccoDHlpyEIMoe c o eltll shy
HeDe HAtCe 2 if) Be OMan8Drqee azISRTp~ XapaKTepoM R He
BCTYllaIJllleS B peaKItBJ) npJC oe~eHHfI
BHSHBaST y romaeHJle TOT ~T ITO llpZ MaJlHX KOHIJeHTpamRX ZJIOpHnshy
Jpound J BeJIlImR8 ROHCTaHlU nllCCOInI~ ROMlJJI8KCa At ce - no o~eBKaIO p aBHa 25IOr 2
5
-HOHa (10- 5_10-4 ) M Korna OR He OKa3lffiaeT BiIIDIHWI 1pound8 BblXOll 3TPlJleHshy
aCTaTNIijlllHa aCTaTXlIOpSTaH ( At hi - CHltCe ) He oopa3yeTCR HOHH
XJIopa HaxolJHIqgtHICH B OKpyxemm lIpOMSXYTOlliOr O ltOMILlIeKCa n0J1EIli
KOmcypHpOBaTlgt C r MIWOKCU-1I0UaMl IIpll 3aBepmemm IIpHc o ellRHBHWI OllHashy
KO KaKHX--JlIOO Iij)yrn rrponyltTOB lllICoellHHemm KpOM8 8TM8Ha cT8TllI1shy
pHHa HB owro oc5uapYlteHO TaRlIM oopa SaM K3Y1eHHafI p earonm IlpKcoelllmeBIDl nOl(TB9p lIOIaeT BH-
CR13aliHOe paHoe BaMIJ IIpeltlIOJIOEeIDle ITO aCTaT IlHClKJlJllpOB~ B BOshy
rltY C TaOllJll3HpyeTCR B ifloIlM8 rWloaCT8THo A KlCJIOTH - At 0 H 3 4 Hanwme ROTOPOH n 03BOJIfI8T ocyme CTBlfTJ p~ rrplllcoellHH9HIUI aCTaT8
K 3TZ1leHY 0 o6p a SOBaIDleM 8TWlBRaCTalTllIIJlmta ITPHCYTCTBlB Mlfitep amHol1
KllCJ[OTli B cpene ( ~~ ce Olj MIl H2S0~ ) YBGJIH1nffiaeT p~OlllJylO onoc o6shy
HOCTh aC T8Ta IIOCKOJlbRY rrep eBOllHT At OH B oOJIee aKTHBBIDt 3JIeKTpOshy
JMbHWi areHT - IrpOTOHHpOBaBHYlO r mIOaCT8 TlfYlO KKC)lOTY Po t OH l bull ITo
Bcell BlflnlMOCTll S1O Ti tlJopMa B Koropoli eCTaT cytIleCTBy eT B BiIle OllH0shyIO
BaJIeHTHOr o KaTlfOH bull B 3aKJIlOIeHH9 aBTOPbI BllJl8ICWOT r JIYooRYla 6JtarOnaPHOCTlgt 13 A Xamurny
3a IIOCTO~ WiTepec It IlamIoil pa6o T9 li ueHllli8 aaMBI3HJotJ1 IO C KOPOTshy
KHHY 38 n OMOmP B IIpoBeneHRH o6~eH~ na YCKopHTe~9 Y-2oo
lIHTepaTypa
1 1I Jle JIB Map P J30JlTOH 3JleKTpocIJHJIbRoe IIprrc o9lOfl19Hll9 K 1J9H8CHIIleHshy
IWM CRC TeMaM MIIp M I968 c94-I79 2 lliHJJOB EA laHReB 11 n OlMeHmllltOBa A liHgtX 1936 T V11I B6 e 909-928 3 Bamapow 11 Hopceen
4 fOBar os L et ol
p 2 ))- 24 0 5 noherenz V a t RI
p 119- 1 1 6 13eitrruu-XliJIIreTaJ
DD xamwl BA JWI CCCp I982 266IH c I20- I22 Ra diochem Rodi oann l l etters 1902 54
~o d l o c h em RR d1oana l l e t ters 13 2 52 N2
MeTOlllJ 3KCU9Ill4MeHTa Tl opramtlecKoli JCmm1
XnmSI M 1968 c 125- 127 7 Vaeoroe L bull bull at AI Rnd1ochem UBrlioAr AI le t ter s 111 1 117 N
p 313- 322 8 Helql8COD EB OCHODll odmen XZMmfa 2T XIoomM 193T I c 28I 9 Yu V Notlleyev V I Kho l k i n J ITlorF ruc l c h ern 1)6fl 3 0
p323J-32 t J ro fiaH r1gty-lt31lB liopc eSB IOB XBnxml BA Tiao Tao-HaRlo laIUiOXIDOOi
1963 5 J~ c 351-355
PyrOITRCb nOCTynnJIa B ll3A3T aITbCKHfi OT~a[
16 aBl~CTa 1985 ro~n
6
OS ~OS os s n p H~1Mll~ TU~ 1(lJ4 ll l4ttlt1) Ha Ilpcnp 1 1-ITbI H coo6weHJ1R OGbeA Io1 Heti HOrO l1 HcTH TYTa
RACP HblX ~Cc JlCIlOU rU IHr~ = Q) cd YCI 3tt ()1U 1l_H oi C Jt~lYKlUl Clfl C T OHMOCT b nOl1rlUC KH liD 12 HecH u ~e HiJ t1 3 A t1-l 11n OvOH1
~ III OKn~4aA ne ~~c~nKY no uT A c n bHWM TeMa l ~ 4 e C K~M K a l e rop MAM gt0 1=iJ(
HHIl EKC TE I1ATI1KA ljeHa nOAn KCI(t1o Q) IW r O A t= t
1 3K CnepHMBH l a fl bl-iaFl centrH 3H tltcJ B~COK~1X 3 HeprHtoi 10 p 80 Kon oco o 2 TeOpen1 L4 eC K a A (l)~aH Ka PblCOK Io1 X 3He p rvr 17 p 80 Ko n sX
is 3 3Kcncp~MeIT jJlb t-laR He~tTpOHHaR ~1I1 3HKa p 80 Kon = ~ I Teope T~4eCK a~ cent~3~K~ HM3K~X 3HeprH~ 8 p 80 Ko n
S t~aTeMan1 Ka p Bo Kon
6 ~AepHaR cneKTpOC Kon~ R H paAHOXHMH R p 80 Kon
7 centgts13HKa RCflbI X 1c10H O B 2 p 85 lton
8 Kp~1oreHlo1K 1 2 p 85 Ko n
g YCKopHTeni-1 p 80 Kon
10 ABTOHan-13auaR 06pafioTK~ 3 Kcne p~HeHT m bHblX
AaHHblX p 80 Kon
11 El~ 4HCn~ - E Jl I Ha fi MaH~M clTIo1Ka H TeXHI1K3 6 p 80 Kon
2 XHM1R p 70 Kon
13 l cXH01 Ka cent ~ 3~14e cKoro 3KcnepHMeHTa 8 p 80 Kon
14 H c cneAoBaH~A TBepA~x Ten 101 ~HAKOCTC~
Fl A e pl-lblMH Me TOA~1r~~1 1 p 70 Kon
15 3Kc ne p ~Mc H larlbHaA ~~3~Ka ~AepH~X pcaK4~~
np~ H~3KHX 3Hep r~AX P 50 Kon
16 n03HHel p ~ ~ H ~H3HKa 3 a~HT~ P 9 0 KOtl
17 Teop~1R KOHAeH c~pO BaHHo ro COC T ORHj1~ Ii p 80 Kon
18 Hc nonb 30 DaHHe pe3 Yfi bT aTo e H Me TOA O B
centYHAa~HT a n b H blX Q41 3 t1 4eCK~X l1Ccne AO Batf Hi1 2 p 35 Ko n S CMe ltfHbl X o 6n a C T A X HayfltH l T CXH~ KH
19 5V1ocentl~3j1Kas ro=~ ~ s 11 l fut Ltlt oI MlJilli Cl Ubl lL cxtJQ PW eHa C JWJ60ro MeCA ~
g r= ni l III I M UIH1L)lC tM oqopM-n eHM A nOAnHCKH c nCAYC TsO
IJi OI1~fl 111)0 cy 10 1000 MocKBa Ill aB no 4TanT tgt COt
= ~ ro = coo o Q) ot[ Q) ~
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o= rOS s I=i 0 c s 0
IS r= a~ ro s() tr s Q)=~ ~O c O 0 o~s
29shy1 n 20 Ko n
a TC WYUl C r o rOAa
06pa1ijaTbcn B 3qa T e Jlb CtltMi1t
nR 79
~80 25 ~ r
u 60 A ~ sect ~
40
_J o 5 10 15 20 25 30 35 MHH l
PRC I 3aBHCHMOCTlgt BHXo~a 3TH~8HacTaTr~KHa
OT BP8MSHE P eaKqHR
l~ =[o 80 i5-50
sect ~I~ 30 ~ t 20
IO
l 0 8 10 n 12 13 gt4 pH
PHC 2 3aBHCHMOCTn BhlXOM 3TMsHacTaTIRlJJ)lma OT
KHC~OTHOCTH cps~
pym88 yqacTRs 6yn8T TIpHHRMaTlgt MeHee peaKlllloHHocnoc06HrtI aJIeKTpOltPRIIDshy
HHll ar8ET - rmzoaCTaTHM KHC~OTa (AtOH ) PaspliB CMSll At- OH 6~eT TIpOllCXO~Tn BHYTpll TIpoMeJKYlOIHOro KOMllJI8Kca BBany Toro ITO rIDIoacshy
TaTEM rurcMTa JIBJIffeTCR cna6blM aJIeKTpoPMoM II ~CCODlaIULI ee ITO OCHOBshy
HOloY Tllny saTpYILHlIT8JThHa) BIDCOn llTRJI8HacT8TIlIlij)KHa nana eT IIpll CMeshy
He KlIc~oA CpSIUl Ha HS~TpamHy1O II mMOffiY ( OTC)lC Blle IlpOIJYKT8 IIpJJshy
J lIID HOn8 KOHCTaHTa rtHCCOIlIaDIIH r OM ITO OCHOBHOMY THITY paBHa 310-10 8
4
COertHHeHIDI B cpene e pH paBHHM 13 H 14 MOJKeT 61iTlgt 06yc~oB~eHo KaK
ITO~aB~eHlIeM ~llCCODl8UID AtOH TaR H BOCCTaHOMeImeM aCTaTa ~O a CTashy
T~) IIOI(06HOS nOBe~eHIle aCTT Ha6iIKu8JIOClgt H B p6aKDIIH aneKTpoPRlIbshy
Horo apoWlT1ll8CKOro SaMem81I11ff 4 bull P8~ HMe8T SaM8THIil1 BIDCO~ TOJThshy
KO upH nO~Hc~eHHlI cpe~
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paCTBOpHTenH-BOIUl Ha ~OpoPOpM CMH~ xnOPoPOPMOM co CT8HOK CT~shy
Hoi aMITY~ aCTaT IIoc~e ero ~C~ C cepe6pa B nyc~ aMIIY~ He
B3aHMO~eftcTBo~ C 3TM8HOM llpll B~epXKBaHIIX p8~OHHOH CMeCH B TSshy
lsmre 2 I8C OB KaK llpll OOC TaR H rrpH 20degC BSPOfITHO llplIcOeIOllieHIlS acshy
TaTa B ~OM c~ae H8 rrpo~CXO~T B~ OTCYTCTBRR He06xo~oro
IIpOTlIBOBOHa lLIm liS ITO llplIIHHe HaxOJleImfI aCTaTa B TPYIUIOAHCcolllillpy eshy
MOM COCTOmIJllll MB B IWyrOH XHMlIIeCKoi ~pMe
IIpR BBe~eHlIH B peaKItlIoHHylO CM8Clgt (aCTaT B 015 M H(lO~+ (Hit 6BXpOMal-ROH8 KOHD8HTpaIUre~ IO-7M HS 6i1I0 OOHapJ)teHO IIpOnyKTOB IIpHshy
CoenHHeHKR acTaTa It 3TRJISHY 3a I laC TIpoBenemm peruanm TIpR OOC lloshy
BHllieHIle TeMIIepaTypli ITO Bcef B~OCTJJ cIIoco6cTBYST ~cco~
ROYnnSRca II IIOSBO~eT nO~HTlgt 3TKnSHaCTaTr~lIH C BHXO~OM ~o
(45 plusmn 4 ) n pR T8MIIsp3Type rexPc 3a I Iac nalte IIpR TaROH BHCOROn KOHshy
oeHTJ)8DIIH 6HXpOMaT-HOHa KaK 1O-2M ilpHCYTCTBIIS B PSaKllIIOHHOi CMecR UOplUt-RoHa IIpHBO~T K CHIDlWHBJO
BllXo~a 3TM8HaCTaTrHIWIDIa (TaM 2)
Tao~a 2 3aBHCRMOCTL BHXOM 3TRJIeHaCTa~lIHa OT KOHIJSHTpaIJHlI
NoCe (YC~OBKff 002 M Heeo T8MIIepaTj1l8 - oOe
BpeMff - 30 MHHyT)
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IBllXO~
( ) 455t35 443plusmn46 48 6plusmn79 22 5plusmn45 i 12 4zP 8
AAaJIOIlIUlYe OIIHTH rrpoBenemme C Hon0M-I31 des HOCJIT9JlJI llOR838shy
JIll no~o6HHe pesymTaTH Bep01JVO ac TaT B KlIc~oi cpene B rrpltCyTcTBmt
XJIOPHn-l[OHa TaK lEe R8R J HOll o 6paay eT TP~O~ccoDHlpyEIMoe c o eltll shy
HeDe HAtCe 2 if) Be OMan8Drqee azISRTp~ XapaKTepoM R He
BCTYllaIJllleS B peaKItBJ) npJC oe~eHHfI
BHSHBaST y romaeHJle TOT ~T ITO llpZ MaJlHX KOHIJeHTpamRX ZJIOpHnshy
Jpound J BeJIlImR8 ROHCTaHlU nllCCOInI~ ROMlJJI8KCa At ce - no o~eBKaIO p aBHa 25IOr 2
5
-HOHa (10- 5_10-4 ) M Korna OR He OKa3lffiaeT BiIIDIHWI 1pound8 BblXOll 3TPlJleHshy
aCTaTNIijlllHa aCTaTXlIOpSTaH ( At hi - CHltCe ) He oopa3yeTCR HOHH
XJIopa HaxolJHIqgtHICH B OKpyxemm lIpOMSXYTOlliOr O ltOMILlIeKCa n0J1EIli
KOmcypHpOBaTlgt C r MIWOKCU-1I0UaMl IIpll 3aBepmemm IIpHc o ellRHBHWI OllHashy
KO KaKHX--JlIOO Iij)yrn rrponyltTOB lllICoellHHemm KpOM8 8TM8Ha cT8TllI1shy
pHHa HB owro oc5uapYlteHO TaRlIM oopa SaM K3Y1eHHafI p earonm IlpKcoelllmeBIDl nOl(TB9p lIOIaeT BH-
CR13aliHOe paHoe BaMIJ IIpeltlIOJIOEeIDle ITO aCTaT IlHClKJlJllpOB~ B BOshy
rltY C TaOllJll3HpyeTCR B ifloIlM8 rWloaCT8THo A KlCJIOTH - At 0 H 3 4 Hanwme ROTOPOH n 03BOJIfI8T ocyme CTBlfTJ p~ rrplllcoellHH9HIUI aCTaT8
K 3TZ1leHY 0 o6p a SOBaIDleM 8TWlBRaCTalTllIIJlmta ITPHCYTCTBlB Mlfitep amHol1
KllCJ[OTli B cpene ( ~~ ce Olj MIl H2S0~ ) YBGJIH1nffiaeT p~OlllJylO onoc o6shy
HOCTh aC T8Ta IIOCKOJlbRY rrep eBOllHT At OH B oOJIee aKTHBBIDt 3JIeKTpOshy
JMbHWi areHT - IrpOTOHHpOBaBHYlO r mIOaCT8 TlfYlO KKC)lOTY Po t OH l bull ITo
Bcell BlflnlMOCTll S1O Ti tlJopMa B Koropoli eCTaT cytIleCTBy eT B BiIle OllH0shyIO
BaJIeHTHOr o KaTlfOH bull B 3aKJIlOIeHH9 aBTOPbI BllJl8ICWOT r JIYooRYla 6JtarOnaPHOCTlgt 13 A Xamurny
3a IIOCTO~ WiTepec It IlamIoil pa6o T9 li ueHllli8 aaMBI3HJotJ1 IO C KOPOTshy
KHHY 38 n OMOmP B IIpoBeneHRH o6~eH~ na YCKopHTe~9 Y-2oo
lIHTepaTypa
1 1I Jle JIB Map P J30JlTOH 3JleKTpocIJHJIbRoe IIprrc o9lOfl19Hll9 K 1J9H8CHIIleHshy
IWM CRC TeMaM MIIp M I968 c94-I79 2 lliHJJOB EA laHReB 11 n OlMeHmllltOBa A liHgtX 1936 T V11I B6 e 909-928 3 Bamapow 11 Hopceen
4 fOBar os L et ol
p 2 ))- 24 0 5 noherenz V a t RI
p 119- 1 1 6 13eitrruu-XliJIIreTaJ
DD xamwl BA JWI CCCp I982 266IH c I20- I22 Ra diochem Rodi oann l l etters 1902 54
~o d l o c h em RR d1oana l l e t ters 13 2 52 N2
MeTOlllJ 3KCU9Ill4MeHTa Tl opramtlecKoli JCmm1
XnmSI M 1968 c 125- 127 7 Vaeoroe L bull bull at AI Rnd1ochem UBrlioAr AI le t ter s 111 1 117 N
p 313- 322 8 Helql8COD EB OCHODll odmen XZMmfa 2T XIoomM 193T I c 28I 9 Yu V Notlleyev V I Kho l k i n J ITlorF ruc l c h ern 1)6fl 3 0
p323J-32 t J ro fiaH r1gty-lt31lB liopc eSB IOB XBnxml BA Tiao Tao-HaRlo laIUiOXIDOOi
1963 5 J~ c 351-355
PyrOITRCb nOCTynnJIa B ll3A3T aITbCKHfi OT~a[
16 aBl~CTa 1985 ro~n
6
OS ~OS os s n p H~1Mll~ TU~ 1(lJ4 ll l4ttlt1) Ha Ilpcnp 1 1-ITbI H coo6weHJ1R OGbeA Io1 Heti HOrO l1 HcTH TYTa
RACP HblX ~Cc JlCIlOU rU IHr~ = Q) cd YCI 3tt ()1U 1l_H oi C Jt~lYKlUl Clfl C T OHMOCT b nOl1rlUC KH liD 12 HecH u ~e HiJ t1 3 A t1-l 11n OvOH1
~ III OKn~4aA ne ~~c~nKY no uT A c n bHWM TeMa l ~ 4 e C K~M K a l e rop MAM gt0 1=iJ(
HHIl EKC TE I1ATI1KA ljeHa nOAn KCI(t1o Q) IW r O A t= t
1 3K CnepHMBH l a fl bl-iaFl centrH 3H tltcJ B~COK~1X 3 HeprHtoi 10 p 80 Kon oco o 2 TeOpen1 L4 eC K a A (l)~aH Ka PblCOK Io1 X 3He p rvr 17 p 80 Ko n sX
is 3 3Kcncp~MeIT jJlb t-laR He~tTpOHHaR ~1I1 3HKa p 80 Kon = ~ I Teope T~4eCK a~ cent~3~K~ HM3K~X 3HeprH~ 8 p 80 Ko n
S t~aTeMan1 Ka p Bo Kon
6 ~AepHaR cneKTpOC Kon~ R H paAHOXHMH R p 80 Kon
7 centgts13HKa RCflbI X 1c10H O B 2 p 85 lton
8 Kp~1oreHlo1K 1 2 p 85 Ko n
g YCKopHTeni-1 p 80 Kon
10 ABTOHan-13auaR 06pafioTK~ 3 Kcne p~HeHT m bHblX
AaHHblX p 80 Kon
11 El~ 4HCn~ - E Jl I Ha fi MaH~M clTIo1Ka H TeXHI1K3 6 p 80 Kon
2 XHM1R p 70 Kon
13 l cXH01 Ka cent ~ 3~14e cKoro 3KcnepHMeHTa 8 p 80 Kon
14 H c cneAoBaH~A TBepA~x Ten 101 ~HAKOCTC~
Fl A e pl-lblMH Me TOA~1r~~1 1 p 70 Kon
15 3Kc ne p ~Mc H larlbHaA ~~3~Ka ~AepH~X pcaK4~~
np~ H~3KHX 3Hep r~AX P 50 Kon
16 n03HHel p ~ ~ H ~H3HKa 3 a~HT~ P 9 0 KOtl
17 Teop~1R KOHAeH c~pO BaHHo ro COC T ORHj1~ Ii p 80 Kon
18 Hc nonb 30 DaHHe pe3 Yfi bT aTo e H Me TOA O B
centYHAa~HT a n b H blX Q41 3 t1 4eCK~X l1Ccne AO Batf Hi1 2 p 35 Ko n S CMe ltfHbl X o 6n a C T A X HayfltH l T CXH~ KH
19 5V1ocentl~3j1Kas ro=~ ~ s 11 l fut Ltlt oI MlJilli Cl Ubl lL cxtJQ PW eHa C JWJ60ro MeCA ~
g r= ni l III I M UIH1L)lC tM oqopM-n eHM A nOAnHCKH c nCAYC TsO
IJi OI1~fl 111)0 cy 10 1000 MocKBa Ill aB no 4TanT tgt COt
= ~ ro = coo o Q) ot[ Q) ~
arro E-lt E-t = gtos E-lt cd os C) E-t
o= rOS s I=i 0 c s 0
IS r= a~ ro s() tr s Q)=~ ~O c O 0 o~s
29shy1 n 20 Ko n
a TC WYUl C r o rOAa
06pa1ijaTbcn B 3qa T e Jlb CtltMi1t
nR 79
-HOHa (10- 5_10-4 ) M Korna OR He OKa3lffiaeT BiIIDIHWI 1pound8 BblXOll 3TPlJleHshy
aCTaTNIijlllHa aCTaTXlIOpSTaH ( At hi - CHltCe ) He oopa3yeTCR HOHH
XJIopa HaxolJHIqgtHICH B OKpyxemm lIpOMSXYTOlliOr O ltOMILlIeKCa n0J1EIli
KOmcypHpOBaTlgt C r MIWOKCU-1I0UaMl IIpll 3aBepmemm IIpHc o ellRHBHWI OllHashy
KO KaKHX--JlIOO Iij)yrn rrponyltTOB lllICoellHHemm KpOM8 8TM8Ha cT8TllI1shy
pHHa HB owro oc5uapYlteHO TaRlIM oopa SaM K3Y1eHHafI p earonm IlpKcoelllmeBIDl nOl(TB9p lIOIaeT BH-
CR13aliHOe paHoe BaMIJ IIpeltlIOJIOEeIDle ITO aCTaT IlHClKJlJllpOB~ B BOshy
rltY C TaOllJll3HpyeTCR B ifloIlM8 rWloaCT8THo A KlCJIOTH - At 0 H 3 4 Hanwme ROTOPOH n 03BOJIfI8T ocyme CTBlfTJ p~ rrplllcoellHH9HIUI aCTaT8
K 3TZ1leHY 0 o6p a SOBaIDleM 8TWlBRaCTalTllIIJlmta ITPHCYTCTBlB Mlfitep amHol1
KllCJ[OTli B cpene ( ~~ ce Olj MIl H2S0~ ) YBGJIH1nffiaeT p~OlllJylO onoc o6shy
HOCTh aC T8Ta IIOCKOJlbRY rrep eBOllHT At OH B oOJIee aKTHBBIDt 3JIeKTpOshy
JMbHWi areHT - IrpOTOHHpOBaBHYlO r mIOaCT8 TlfYlO KKC)lOTY Po t OH l bull ITo
Bcell BlflnlMOCTll S1O Ti tlJopMa B Koropoli eCTaT cytIleCTBy eT B BiIle OllH0shyIO
BaJIeHTHOr o KaTlfOH bull B 3aKJIlOIeHH9 aBTOPbI BllJl8ICWOT r JIYooRYla 6JtarOnaPHOCTlgt 13 A Xamurny
3a IIOCTO~ WiTepec It IlamIoil pa6o T9 li ueHllli8 aaMBI3HJotJ1 IO C KOPOTshy
KHHY 38 n OMOmP B IIpoBeneHRH o6~eH~ na YCKopHTe~9 Y-2oo
lIHTepaTypa
1 1I Jle JIB Map P J30JlTOH 3JleKTpocIJHJIbRoe IIprrc o9lOfl19Hll9 K 1J9H8CHIIleHshy
IWM CRC TeMaM MIIp M I968 c94-I79 2 lliHJJOB EA laHReB 11 n OlMeHmllltOBa A liHgtX 1936 T V11I B6 e 909-928 3 Bamapow 11 Hopceen
4 fOBar os L et ol
p 2 ))- 24 0 5 noherenz V a t RI
p 119- 1 1 6 13eitrruu-XliJIIreTaJ
DD xamwl BA JWI CCCp I982 266IH c I20- I22 Ra diochem Rodi oann l l etters 1902 54
~o d l o c h em RR d1oana l l e t ters 13 2 52 N2
MeTOlllJ 3KCU9Ill4MeHTa Tl opramtlecKoli JCmm1
XnmSI M 1968 c 125- 127 7 Vaeoroe L bull bull at AI Rnd1ochem UBrlioAr AI le t ter s 111 1 117 N
p 313- 322 8 Helql8COD EB OCHODll odmen XZMmfa 2T XIoomM 193T I c 28I 9 Yu V Notlleyev V I Kho l k i n J ITlorF ruc l c h ern 1)6fl 3 0
p323J-32 t J ro fiaH r1gty-lt31lB liopc eSB IOB XBnxml BA Tiao Tao-HaRlo laIUiOXIDOOi
1963 5 J~ c 351-355
PyrOITRCb nOCTynnJIa B ll3A3T aITbCKHfi OT~a[
16 aBl~CTa 1985 ro~n
6
OS ~OS os s n p H~1Mll~ TU~ 1(lJ4 ll l4ttlt1) Ha Ilpcnp 1 1-ITbI H coo6weHJ1R OGbeA Io1 Heti HOrO l1 HcTH TYTa
RACP HblX ~Cc JlCIlOU rU IHr~ = Q) cd YCI 3tt ()1U 1l_H oi C Jt~lYKlUl Clfl C T OHMOCT b nOl1rlUC KH liD 12 HecH u ~e HiJ t1 3 A t1-l 11n OvOH1
~ III OKn~4aA ne ~~c~nKY no uT A c n bHWM TeMa l ~ 4 e C K~M K a l e rop MAM gt0 1=iJ(
HHIl EKC TE I1ATI1KA ljeHa nOAn KCI(t1o Q) IW r O A t= t
1 3K CnepHMBH l a fl bl-iaFl centrH 3H tltcJ B~COK~1X 3 HeprHtoi 10 p 80 Kon oco o 2 TeOpen1 L4 eC K a A (l)~aH Ka PblCOK Io1 X 3He p rvr 17 p 80 Ko n sX
is 3 3Kcncp~MeIT jJlb t-laR He~tTpOHHaR ~1I1 3HKa p 80 Kon = ~ I Teope T~4eCK a~ cent~3~K~ HM3K~X 3HeprH~ 8 p 80 Ko n
S t~aTeMan1 Ka p Bo Kon
6 ~AepHaR cneKTpOC Kon~ R H paAHOXHMH R p 80 Kon
7 centgts13HKa RCflbI X 1c10H O B 2 p 85 lton
8 Kp~1oreHlo1K 1 2 p 85 Ko n
g YCKopHTeni-1 p 80 Kon
10 ABTOHan-13auaR 06pafioTK~ 3 Kcne p~HeHT m bHblX
AaHHblX p 80 Kon
11 El~ 4HCn~ - E Jl I Ha fi MaH~M clTIo1Ka H TeXHI1K3 6 p 80 Kon
2 XHM1R p 70 Kon
13 l cXH01 Ka cent ~ 3~14e cKoro 3KcnepHMeHTa 8 p 80 Kon
14 H c cneAoBaH~A TBepA~x Ten 101 ~HAKOCTC~
Fl A e pl-lblMH Me TOA~1r~~1 1 p 70 Kon
15 3Kc ne p ~Mc H larlbHaA ~~3~Ka ~AepH~X pcaK4~~
np~ H~3KHX 3Hep r~AX P 50 Kon
16 n03HHel p ~ ~ H ~H3HKa 3 a~HT~ P 9 0 KOtl
17 Teop~1R KOHAeH c~pO BaHHo ro COC T ORHj1~ Ii p 80 Kon
18 Hc nonb 30 DaHHe pe3 Yfi bT aTo e H Me TOA O B
centYHAa~HT a n b H blX Q41 3 t1 4eCK~X l1Ccne AO Batf Hi1 2 p 35 Ko n S CMe ltfHbl X o 6n a C T A X HayfltH l T CXH~ KH
19 5V1ocentl~3j1Kas ro=~ ~ s 11 l fut Ltlt oI MlJilli Cl Ubl lL cxtJQ PW eHa C JWJ60ro MeCA ~
g r= ni l III I M UIH1L)lC tM oqopM-n eHM A nOAnHCKH c nCAYC TsO
IJi OI1~fl 111)0 cy 10 1000 MocKBa Ill aB no 4TanT tgt COt
= ~ ro = coo o Q) ot[ Q) ~
arro E-lt E-t = gtos E-lt cd os C) E-t
o= rOS s I=i 0 c s 0
IS r= a~ ro s() tr s Q)=~ ~O c O 0 o~s
29shy1 n 20 Ko n
a TC WYUl C r o rOAa
06pa1ijaTbcn B 3qa T e Jlb CtltMi1t
nR 79